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The whole problem is that in order for a substitution reaction to occur (whether it be S N 2 or acyl substitution) you need a decent leaving group

Freezing is excellent for long-term storage (months), but it's terrible if you need to access the peptide frequently

One of the reasons researchers got interested in it is that it appears to be involved in signaling related to tissue repair and regeneration

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Add secondary peptides after establishing tolerance and seeing results